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81.
A modified version of the Multimedia Activity Model for Ionics MAMI, including two-layered atmosphere, air-water interface partitioning, intermittent rainfall and variable cloud coverage was developed to simulate the atmospheric fate of ten low volatility or ionizable organic chemicals. Probabilistic simulations describing the uncertainty of substance and environmental input properties were run to evaluate the impact of atmospheric parameters, ionization and air-water (or air-ice) interface enrichment.The rate of degradation and the concentration of OH radicals, the duration of dry and wet periods, and the parameters describing air-water partitioning (KAW and temperature) and ionization (pKa and pH) are the key parameters determining the potential for long range transport. Wet deposition is an important removal process, but its efficiency is limited, primarily by the duration of the dry period between precipitation events.Given the underlying model assumptions, the presence of clouds contributes to the higher persistence in the troposphere because of the capacity of cloud water to accumulate and transport non-volatile (e.g. 2,4-D) and surface-active chemicals (e.g. PFOA). This limits the efficiency of wet deposition from the troposphere enhancing long-range transport. 相似文献
82.
Boxman AW Peters RC Roelofs JG 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):1252-1259
In a Scots pine forest the throughfall deposition and the chemical composition of the soil solution was monitored since 1984. (Inter)national legislation measures led to a reduction of the deposition of nitrogen and sulphur. The deposition of sulphur has decreased by approximately 65%. The total mineral-nitrogen deposition has decreased by ca. 25%, which is mainly due to a reduction in ammonium-N deposition (−40%), since nitrate-N deposition has increased (+50%). The nitrogen concentration in the upper mineral soil solution at 10 cm depth has decreased, leading to an improved nutritional balance, which may result in improved tree vitality. In the drainage water at 90 cm depth the fluxes of NO3− and SO42− have decreased, resulting in a reduced leeching of accompanying base cations, thus preserving nutrients in the ecosystem. It may take still several years, however, before this will meet the prerequisite of a sustainable ecosystem. 相似文献
83.
Comparison of forest edge effects on throughfall deposition in different forest types 总被引:2,自引:0,他引:2
Wuyts K De Schrijver A Staelens J Gielis L Vandenbruwane J Verheyen K 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):854-861
This study examined the influence of distance to the forest edge, forest type, and time on Cl−, SO42−, NO3−, and NH4+ throughfall deposition in forest edges. The forests were dominated by pedunculate oak, silver birch, or Corsican/Austrian pine, and were situated in two regions of Flanders (Belgium). Along transects, throughfall deposition was monitored at distances of 0-128 m from the forest edge. A repeated-measures analysis demonstrated that time, forest type, and distance to the forest edge significantly influenced throughfall deposition of the ions studied. The effect of distance to the forest edge depended significantly on forest type in the deposition of Cl−, SO42−, and NO3−: the edge effect was significantly greater in pine stands than in deciduous birch and oak stands. This finding supports the possibility of converting pine plantations into oak or birch forests in order to mitigate the input of nitrogen and potentially acidifying deposition. 相似文献
84.
Kuang YW Zhou GY Da Wen Z Liu SZ 《Environmental science and pollution research international》2007,14(4):270-275
Goal, Scope and Background Rapid urbanization and the expansion of industrial activities in the past several decades have led to large increases in emissions
of pollutants in the Pearl River Delta of south China. Recent reports have suggested that industrial emission is a major factor
contributing to the damages in current natural ecosystem in the Delta area. Tree barks have been used successfully to monitor
the levels of atmospheric metal deposition in many areas, but rarely in China. This study aimed at determining whether atmospheric
heavy metal deposition from a Pb-Zn smeltery at Qujiang, Guangdong province, could be accurately reflected both in the inner
bark and the outer bark of Masson pine (Pinus massoniana L.). The impact of the emission from smeltery on the soils beneath the trees and the relationships of the concentrations
between the soils and the barks were also analyzed.
Methods Barks around the bole of Pinus massoniana from a pine forest near a Pb-Zn smeltery at Qujiang and a reference forest at Dinghushan natural reserve were sampled with
a stainless knife at an average height of 1.5 m above the ground. Mosses and lichens on the surface barks were cleaned prior
to sampling. The samples were carefully divided into the inner bark (living part) and the outer bark (dead part) in the laboratory,
and dried and ground, respectively. After being dry-ashed, the powder of the barks was dissolved in HNO3. The solutions were analyzed for iron (Fe), manganese (Mn), copper (Cu), zinc (Zn), chromium (Cr), nickel (Ni) and cobalt
(Co) by inductively coupled plasmas emission spectrometry (ICP, PS-1000AT, USA) and Cadmium (Cd) and lead (Pb) by graphite
furnace atomic absorption spectrometry (GFAAS, ZEENIT 60, Germany). Surface soils (0–10 cm) beneath the sample trees were
also collected and analyzed for the selected metals.
Results and Discussion Concentrations of the selected metals in soils at Qujiang were far above their environmental background values in the area,
except for Fe and Mn, whilst at Dinghushan, they were far below their background values, except for Cd and Co. Levels of the
metals, in particular Pb and Zn, in the soils beneath the sample trees at Qujiang were higher than those at Dinghushan with
statistical significance. The result suggested that the pine forest soils at Qujiang had a great input of heavy metals from
wet and dry atmospheric deposition, with the Pb-Zn smeltery most probably being the source.
Levels of Cu, Fe, Mn, Zn, Ni and Pb at Qujiang, both in the inner and the outer bark, were statistically higher than those
at Dinghushan. Higher concentrations of Pb, Fe, Zn and Cu may come from the stem-flow of elements leached from the canopy,
soil splash on the 1.5 m height and sorption of metals in the mosses and lichens growing on the bark, which were direct or
indirect results from the atmospheric deposition. Levels of heavy metals in the outer barks were associated well with the
metal concentrations in the soil, reflecting the close relationships between the metal atmospheric deposition and their accumulation
in the outer bark of Masson pine. The significant (p<0.01) correlations of Fe-Cu, Fe-Cr, Fe-Pb, Fe-Ni, Pb-Ni, and Pb-Zn in
the outer barks at Qujiang again suggested a common source for the metals. The correlation only occurred between Pb and Ni,
Cd and Co in the outer barks at Dinghushan, which suggested that those metals must possibly have other uncommon sources.
Conclusions Atmospheric deposition of the selected metals was great at Qujiang, based on the levels in the bark of Pinus massoniana and on the concentrations in the soils beneath the trees compared with that at Dinghushan. Bark of Pinus massoniana, especially the outer bark, was an indicator of metal loading at least at the time of sampling.
Recommendations and Perspectives The results from this study and the techniques employed constituted a new contribution to the development of biogeochemical
methods for environmental monitoring particularly in areas with high frequency of pollution in China. The method would be
of value for follow up studies aimed at the assessment of industrial pollution in other areas similar with the Pearl River
Delta. 相似文献
85.
Stevens CJ Duprè C Dorland E Gaudnik C Gowing DJ Bleeker A Diekmann M Alard D Bobbink R Fowler D Corcket E Mountford JO Vandvik V Aarrestad PA Muller S Dise NB 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2243-2250
A survey of 153 acid grasslands from the Atlantic biogeographic region of Europe indicates that chronic nitrogen deposition is changing plant species composition and soil and plant-tissue chemistry. Across the deposition gradient (2-44 kg N ha−1 yr−1) grass richness as a proportion of total species richness increased whereas forb richness decreased. Soil C:N ratio increased, but soil extractable nitrate and ammonium concentrations did not show any relationship with nitrogen deposition. The above-ground tissue nitrogen contents of three plant species were examined: Agrostis capillaris (grass), Galium saxatile (forb) and Rhytidiadelphus squarrosus (bryophyte). The tissue nitrogen content of neither vascular plant species showed any relationship with nitrogen deposition, but there was a weak positive relationship between R. squarrosus nitrogen content and nitrogen deposition. None of the species showed strong relationships between above-ground tissue N:P or C:N and nitrogen deposition, indicating that they are not good indicators of deposition rate. 相似文献
86.
Tree barks were used as biomonitors to evaluate past atmospheric pollution within and around the industrial zones of Strasbourg (France) and Kehl (Germany) in the Rhine Valley. The here estimated residence time for trace metals, PCBs and PCDD/Fs in tree bark is >10 years. Thus, all pollution observed by tree bark biomonitoring can be older than 10 years. The PCB baseline concentration (sum of seven PCB indicators (Σ7PCBind)) determined on tree barks from a remote area in the Vosges mountains is 4 ng g−1 and corresponds to 0.36 × 10−3 ng toxic equivalent (TEQ) g−1 for the dioxin-like PCBs (DL-PCBs). The northern Rhine harbor suffered especially from steel plant, waste incinerator and thermal power plant emissions. The polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/Fs) concentrations analyzed in tree barks from this industrial area range between 392 and 1420 ng kg−1 dry-weight (dw) corresponding to 3.9 ng TEQPCDD/Fs kg−1 to 17.8 ng TEQPCDD/Fs kg−1, respectively. Highest PCDD/F values of 7.2 ng TEQ kg−1 to 17.8 ng TEQ kg−1 have been observed close to and at a distance of <2 km southwest of the chemical waste incinerator. However, very close to this incinerator lowest TEQ dioxin-like PCB (TEQDL-PCB) values of 0.006 ng TEQ g−1 have been found. On the other hand close to and southwest and northeast of the steel plant the values are comparatively higher and range between 0.011 ng TEQ g−1 and 0.026 ng TEQ g−1. However, even stronger Σ7PCBind enrichments have been observed at a few places in the city center of Kehl, where ΣDL-PCB values of up to 0.11 ng TEQ g−1 have been detected. These enrichments, however, are the result of ancient pollutions since recent long-term measurements at the same sites indicate that the atmospheric PCB concentrations are close to baseline. Emissions from an old landfill of waste and/or great fires might have been the reasons of these PCB enrichments. Other urban environments of the cities of Kehl and Strasbourg show significantly lower Σ7PCBind concentrations. They suffer especially from road and river traffic and have typically Σ7PCBind concentrations ranging from 11 ng g−1 to 29 ng g−1. The PCB concentration of 29 ng g−1 has been found in tree bark close to the railway station of Strasbourg. Nevertheless, the corresponding TEQDL-PCB are low and range between 0.2 × 10−3 ng TEQ g−1 and 7 × 10−3 ng TEQ g−1. Samples collected near road traffic are enriched in Fe, Sb, Sn and Pb. Cd enrichments were found close to almost all types of industries. Rural environments not far from industrial sites suffered from organic and inorganic pollution. In this case, TEQDL-PCB values may reach up to 58 × 10−3 ng TEQ g−1 and the corresponding V, Cr, Co, Ni, and Cd concentrations are comparatively high. 相似文献
87.
Empirical and simulated critical loads for nitrogen deposition in California mixed conifer forests 总被引:2,自引:0,他引:2
Fenn ME Jovan S Yuan F Geiser L Meixner T Gimeno BS 《Environmental pollution (Barking, Essex : 1987)》2008,155(3):492-511
Empirical critical loads (CL) for N deposition were determined from changes in epiphytic lichen communities, elevated NO(3)(-) leaching in streamwater, and reduced fine root biomass in ponderosa pine (Pinus ponderosa Dougl. ex Laws.) at sites with varying N deposition. The CL for lichen community impacts of 3.1kg ha(-1) year(-1) is expected to protect all components of the forest ecosystem from the adverse effects of N deposition. Much of the western Sierra Nevada is above the lichen-based CL, showing significant changes in lichen indicator groups. The empirical N deposition threshold and that simulated by the DayCent model for enhanced NO(3)(-)leaching were 17kg N ha(-1) year(-1). DayCent estimated that elevated NO(3)(-) leaching in the San Bernardino Mountains began in the late 1950s. Critical values for litter C:N (34.1), ponderosa pine foliar N (1.1%), and N concentrations (1.0%) in the lichen Letharia vulpina ((L.) Hue) are indicative of CL exceedance. 相似文献
88.
Yuanhang Zhang Yuesi Wang Xin Jin Zirui Liu Gehui Wang Guiqian Tang Keding Lu Bo Hu Shanshan Wang Guohui Li Xinqin An Chao Wang Qihou Hu Lingyan He Fenfen Zhang 《环境科学学报(英文版)》2023,123(1):350-366
Atmospheric oxidizing capacity (AOC) is an essential driving force of troposphere chemistry and self-cleaning, but the definition of AOC and its quantitative representation remain uncertain. Driven by national demand for air pollution control in recent years, Chinese scholars have carried out studies on theories of atmospheric chemistry and have made considerable progress in AOC research. This paper will give a brief review of these developments. First, AOC indexes were established that represent apparent atmospheric oxidizing ability (AOIe) and potential atmospheric oxidizing ability (AOIp) based on aspects of macrothermodynamics and microdynamics, respectively. A closed study refined the quantitative contributions of heterogeneous chemistry to AOC in Beijing, and these AOC methods were further applied in Beijing-Tianjin-Hebei and key areas across the country. In addition, the detection of ground or vertical profiles for atmospheric OH·, HO2·, NO3· radicals and reservoir molecules can now be obtained with domestic instruments in diverse environments. Moreover, laboratory smoke chamber simulations revealed heterogeneous processes involving reactions of O3 and NO2, which are typical oxidants in the surface/interface atmosphere, and the evolutionary and budgetary implications of atmospheric oxidants reacting under multispecies, multiphase and multi-interface conditions were obtained. Finally, based on the GRAPES-CUACE adjoint model improved by Chinese scholars, simulations of key substances affecting atmospheric oxidation and secondary organic and inorganic aerosol formation have been optimized. Normalized numerical simulations of AOIe and AOIp were performed, and regional coordination of AOC was adjusted. An optimized plan for controlling O3 and PM2.5 was analyzed by scenario simulation. 相似文献
89.
Yuanhang Zhang Yanhui Liu Jiayin Li Yufang M Ming Zhou Zhaofeng Tan Limin Zeng Keding Lu 《环境科学学报(英文版)》2023,123(1):522-534
The atmospheric chemical mechanism is an essential component of airshed models used for investigating the chemical behaviors and impacts of species. Since the first tropospheric chemical mechanism was proposed in the 1960s, various mechanisms including Master Chemical Mechanism (MCM), Carbon Bond Mechanism (CBM), Statewide Air Pollution Research Center (SAPRC) and Regional Atmospheric Chemistry Mechanism (RACM) have been developed for different research purposes. This work summarizes the development and applications of these mechanisms, introduces their compositions and lumping methods, and compares the ways the mechanisms treat radicals with box model simulations. CBM can reproduce urban pollution events with relatively low cost compared to SAPRC and RACM, whereas the chemical behaviors of radicals and the photochemical production of ozone are described in detail in RACM. The photolysis rates of some oxygenated compounds are low in SAPRC07, which may result in underestimation of radical levels. As an explicit chemical mechanism, MCM describes the chemical processes of primary pollutants and their oxidation products in detail. MCM can be used to investigate certain chemical processes; however, due to its large size, it is rarely used in regional model simulations. A box model case study showed that the chemical behavior of OH and HO2 radicals and the production of ozone were well described by all mechanisms. CBM and SAPRC underestimated the radical levels for different chemical treatments, leading to low ozone production values in both cases. MCM and RACM are widely used in box model studies, while CBM and SAPRC are often selected in regional simulations. 相似文献
90.
Xiaolan Li Guiqian Tang Liguang Li Weijun Quan Yangfeng Wang Ziqi Zhao Ningwei Liu Ye Hong Yanjun Ma 《环境科学学报(英文版)》2022,34(3):300-310
Visibility observed at different altitudes is favorable to understand the causes of air pollution. We conducted 4-years of observations of visibility at 2.8 and 60 m and particulate matter(PM) concentrations from 2015 to 2018 in Shenyang, a provincial city in Northeast China. The results indicated that visibility increased with the increasing height in winter(especially at night), and decreased with height in summer(especially at the daytime). PM concentration exhibited opposite vertical variati... 相似文献